Mono- and Bimetallic Rhodium(I) Complexes Supported by New <i>C</i><sub>2</sub>-Symmetric Bis-N-heterocyclic Carbene Ligands: Metalation via CC Bond Cleavage under Mild Conditions
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The first example of a tethered chiral enetetramine is presented along with its mild metalation with Rh(I) sources to produce chiral, bis-N-heterocyclic carbene complexes. Subtle steric effects determine whether an enetetramine is accessible versus a free biscarbene.
创建时间:
2007-10-22



