Research data supporting "Semi-artificial leaf interfacing organic semiconductors and enzymes for solar chemical synthesis"

Raw data supporting article: Semi-artificial leaf interfacing organic semiconductors and enzymes for solar chemical synthesis. Semi-artificial photoelectrochemical devices are an emerging platform for selective and tunable solar fuel synthesis, but commonly rely on expensive sacrificial agents or diffusional redox mediators that can lead to unwanted side or back reactions. Here, organic semiconductors are interfaced with H2 or formate-producing enzymes, and the co-immobilization with carbonic anhydrase supports biocatalysis in a benign pH neutral bicarbonate buffer. This biohybrid platform allows for O2 evolution coupled to clean formate production, which can be used directly without purification to drive the ruthenium-catalyzed enantioselective asymmetric hydrogenation of acetophenone, offering a promising pathway towards sustainable biohybrid chemical refineries. Manuscript - contains Figures1-5: schematic diagram, electrochemical protein-film voltammetry (PFV) curves, electrochemical controlled potential electrolysis (CPE), photoelectrochemical PFV and CPE (as CSV, PDF, TIF, XLSX files) Supplemental Information - contains Fig.S1-S51: PFV, CPE, SEM, EDX, TEM, COMSOL modelling information, UV-vis, XRD, EIS, photograph, EIS (as TIF, PNG, XLSX, MNOVA files) For more details about the experimental procedure, instrumentation, and data collection, see the manuscript and also the readme txt file.