Developments in Meyers’ Lactamization Methodology: En Route to Bi(hetero)aryl Structures with Defined Axial Chirality
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https://figshare.com/articles/dataset/Developments_in_Meyers_Lactamization_Methodology_En_Route_to_Bi_hetero_aryl_Structures_with_Defined_Axial_Chirality/2385967
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资源简介：
Highly
atroposelective Meyers’ lactamization promoted by
pivalic acid under microwave irradiation is reported which allows
the construction of nonracemic substituted-dibenzo(di)azepine derivatives
through a center to axial chirality transfer principle, controlling
the otherwise configurationally labile biaryl axis. This approach
provides a straightforward entry to enantioenriched analogues of biorelevant
architectures.
创建时间：
2016-02-19
