Microscopic rate constants, activation enthalpies (kcal mol-1) and entropies (cal mol-1 K-1) determined from the global fit of the ps-ms entire time course (at 1 and 0.1 atm CO) of CO rebinding kinetics to Tf-trHb at 20°C.
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https://figshare.com/articles/dataset/_Microscopic_rate_constants_activation_enthalpies_kcal_mol_1_and_entropies_cal_mol_1_K_1_determined_from_the_global_fit_of_the_ps_ms_entire_time_course_at_1_and_0_1_atm_CO_of_CO_rebinding_kinetics_to_Tf_trHb_at_20_176_C_/283752
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Activation enthalpies ΔH‡ and entropies ΔS‡ were estimated from the linear Eyring plots for each rate constant ki in the temperature range 10–30°C, according to the equation: ln(hki/kBT) ) = ΔS‡/R – ΔH‡/RT, where R is the gas constant, h is Planck’s constant, and kB is Boltzmann constant.
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2015-12-02
