Synthesis and Resolution of Chiral Ruthenium Complexes Containing the 1‑Me-3-PhCp Ligand
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https://figshare.com/articles/dataset/Synthesis_and_Resolution_of_Chiral_Ruthenium_Complexes_Containing_the_1_Me_3_PhCp_Ligand/2090905
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资源简介：
A new
ruthenium chloride complex featuring chirality derived from
the face-specific coordination of the 1-Me-3-PhCp ligand has been
successfully synthesized and resolved. The resolution has been achieved
via the diastereomers of the (S)-α-methyl-benzenemethanethiolate
complex (1-Me-3-PhCp)Ru(dppm){(S)-C(S)(H)(Ph)(Me)}.
The X-ray structures of (SCp,S)-(1-Me-3-PhCp)Ru(dppm){C(S)(H)(Ph)(Me)} and (RCp,S)-(1-Me-3-PhCp)Ru(dppm){C(S)(H)(Ph)(Me)}
have been determined. Racemization has been observed at elevated temperatures,
but a room-temperature conversion pathway provides access to the corresponding
enantiopure acetonitrile, chloride, and hydride complexes.
创建时间：
2016-02-12
