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Synthesis and Structure of Seven-Membered Metallacyclic Alkynes

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https://figshare.com/articles/dataset/Synthesis_and_Structure_of_Seven_Membered_Metallacyclic_Alkynes/3299362
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The zirconocene−ethylene complex and (Z)-1,4-bis(trimethylsilyl)-1,2,3-butatriene reacted to give a mixture of 1-zirconacyclopent-3-yne and 1-zirconacyclohept-3-yne. A zirconocene−alkyne complex gave, on the other hand, 1-zirconacyclohept-2-en-5-yne, which was structurally characterized as the major product along with a lesser amount of 1-zirconacyclopent-3-yne.
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2016-05-06
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