Synthesis of a 1,3-Bridged Macrobicyclic Enyne via Chemoselective Cycloisomerization Using Palladium-Catalyzed Alkyne–Alkyne Coupling
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https://figshare.com/articles/dataset/Synthesis_of_a_1_3-Bridged_Macrobicyclic_Enyne_via_Chemoselective_Cycloisomerization_Using_Palladium-Catalyzed_Alkyne_Alkyne_Coupling/4012368
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A unique intramolecular Pd-catalyzed alkyne–alkyne coupling is presented. This transformation generates a strained, 1,3-bridged, macrocyclic enyne. The process was readily executed on gram scale, and the structure of the product was elucidated via X-ray crystallographic analysis. A mechanistic rationale for the observed chemoselectivity is provided.
创建时间：
2016-10-17
