Enantioselective Synthesis of P-Stereogenic Benzophospholanes via Palladium-Catalyzed Intramolecular Cyclization
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下载链接:
https://figshare.com/articles/dataset/Enantioselective_Synthesis_of_P_Stereogenic_Benzophospholanes_via_Palladium_Catalyzed_Intramolecular_Cyclization/3019153
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资源简介:
Enantioselective or diastereoselective intramolecular cyclization of functionalized secondary phosphines or their borane adducts catalyzed by
chiral Pd(diphosphine) complexes gave P-stereogenic benzophospholanes in up to 70% ee. These results provide a new method for the
synthesis of chiral phospholanes, which are valuable ligands in asymmetric catalysis.
创建时间:
2016-02-29



