five

Anion-Dependent Assembly of Cyclic Structure

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Anion_Dependent_Assembly_of_Cyclic_Structure/3240595
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资源简介:
Five Keggin-based metal complexes, [Ag3(2,4‘-bipy)3PMo12O40] (1), [Ag4(2,4‘-bipy)4SiW12O40] (2), [Ag3(2,4‘-bipy)4PW12O40] (3), [Cu4(2,4‘-bipy)4SiW12O40] (4), and [Cu3(2,4‘-bipy)4PW12O40] (5) (2,4‘-bipy = 2,4‘-bipyridine), were synthesized and structurally characterized. Among them, complexes 1, 2, and 4 show a cyclic structure, while complexes 3 and 5 exhibit a one-dimensional (1D) chain structure. Investigation of their structural differences reveals that anions play a key role in the formation of a cyclic structure.
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2006-02-01
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