Templated Synthesis, Postsynthetic Metal Exchange, and Properties of a Porphyrin-Encapsulating Metal–Organic Material
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https://figshare.com/articles/dataset/Templated_Synthesis_Postsynthetic_Metal_Exchange_and_Properties_of_a_Porphyrin_Encapsulating_Metal_Organic_Material/2558680
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资源简介：
Reaction of biphenyl-3,4′,5-tricarboxylate (H3BPT) and CdCl2 in the presence of meso-tetra(N-methyl-4-pyridyl)porphine tetratosylate
(TMPyP) afforded porph@MOM-10, a microporous
metal–organic material containing CdTMPyP cations
encapsulated in an anionic Cd(II) carboxylate framework, [Cd6(BPT)4Cl4(H2O)4]. Porph@MOM-10 is a versatile platform that undergoes exchange
to serve as the parent of a series of porph@MOMs that
exhibit permanent porosity and heterogeneous catalytic activity.
创建时间：
2012-01-18
