Adsorption Data for Activated WUT-1′(Ni) and WUT-2′(Ni) Materials

This dataset contains adsorption isotherms for activated porous materials WUT-1′(Ni) and WUT-2′(Ni), derived from the removal of guest solvent molecules from WUT-1(Ni) and WUT-2(Ni), respectively. Both compounds are based on the same decanuclear nickel(II) hydroxyquinolinato-carbonato cluster, with the molecular formula [Ni10(μ6-CO3)4(L)12], where L = 2-hydroxyquinolinate. Depending on crystallization conditions, the clusters self-assemble into two distinct porous network topologies: diamondoid (WUT-1) or pyrite-type (WUT-2). The materials exhibit reversible phase transitions and selective gas separation properties. The dataset includes raw experimental adsorption isotherms in the Adsorption Information File (AIF) format for various gases and temperatures.