Study of Cascade Ring-Closing Metathesis Reactions en Route to an Advanced Intermediate of Taxol
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https://figshare.com/articles/dataset/Study_of_Cascade_Ring-Closing_Metathesis_Reactions_en_Route_to_an_Advanced_Intermediate_of_Taxol/4276805
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资源简介：
A highly functionalized intermediate
in the synthesis of Taxol
has been synthesized, which features the tricyclic core and the required
oxygen substituents at C1, C2, C7, C10, and C13. The key step, a ring-closing
dienyne metathesis (RCDEYM) reaction, has been thoroughly optimized
to favor the tricyclic product over the undesired bicyclic product
resulting from diene metathesis.
创建时间：
2016-12-02
