Coupling of Coordinated 2-Iminophosphorano-1-phosphaallyl Leading to Bridged Iminophosphoranato Complexes of Zirconium and Hafnium

NIAID Data Ecosystem2026-03-06 收录

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https://figshare.com/articles/dataset/Coupling_of_Coordinated_2-Iminophosphorano-1-phosphaallyl_Leading_to_Bridged_Iminophosphoranato_Complexes_of_Zirconium_and_Hafnium/3609933

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Reaction of MCl4 (M = Zr, Hf) with 2 equiv of 2-iminophosphorano-1-phosphaallyl lithium [Li{P(Ph)C(CHPh)P(Me)2NSiMe3}(THF)1.5] (1) affords ligand coupling complexes 3 and 4, respectively, while similar treatment of ZrCl4 with [Li{P(Ph)C(C(SiMe2But)Ph)P(Me)2NSiMe3}(THF)2] (2) yields ligand transfer complex 5.

创建时间：

2016-08-17