1‑Chloroalumole
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https://figshare.com/articles/dataset/1_Chloroalumole/19153817
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资源简介:
A representative of the stable alumoles
with a chlorine substituent
at the aluminum atom was synthesized by the coupling of a cyclobutadiene
dianion derivative and aluminum trichloride. The structure of alumole
was established by X-ray crystallography, which showed that alumole
exists as a monomer. The aluminum atom is tetracoordinated with the
fourth coordination site occupied by a thf molecule, which reduces
the intrinsically high Lewis acidity of the aluminum center, thus
stabilizing the alumole molecule.
创建时间:
2022-02-10



