Synthesis and Characterization of Highly Water Soluble Ruthenium(II) and Osmium(II) Complexes Bearing Chelating Sulfonated N‑Heterocyclic Carbene Ligands
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_Highly_Water_Soluble_Ruthenium_II_and_Osmium_II_Complexes_Bearing_Chelating_Sulfonated_N_Heterocyclic_Carbene_Ligands/2445514
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资源简介：
The synthesis of highly water soluble ruthenium(II) and
osmium(II)
complexes based on chelating N-heterocyclic carbene (NHC) ligands
bearing sulfonated side chains is reported. The complexes are easily
accessible in very good yields via synthesis of silver-bis(NHC) complexes
and subsequent reaction
with [(p-cymene)MCl2]2 (M =
Ru, Os). They express high thermal stability and are highly soluble
in water (up to 400 mg/mL). The first structurally characterized Ru(II)
complex bearing a chelating sulfonated ligand is presented.
创建时间：
2016-02-19
