Exogenous Nitrile Substrate Hydroxylation by a New Dicopper-Hydroperoxide Complex
收藏NIAID Data Ecosystem2026-03-06 收录
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A dicopper(I)/phenol-ligand complex in RCN solvents reacts with O2 producing a μ-1,1-hydroperoxo dicopper(II) species. Subsequent thermal transformation results in nitrile hydroxylation and elimination of cyanide, as revealed by the isolation in comparable yields of (i) a cyanide-bridged tetranuclear cluster complex and (ii) benzaldehyde (for R = PhCH2); 18O labeling confirms that the PhC(O)H oxygen atom derives from O2.
创建时间：
2016-05-05
