New Rhodium(I) Carbene Complexes from Carbene Transfer Reactions
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https://figshare.com/articles/dataset/New_Rhodium_I_Carbene_Complexes_from_Carbene_Transfer_Reactions/3226132
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资源简介：
The Rh(I) complexes RhCl(diene)(NHC) have been synthesized from Ag(I) carbene precursors, where
NHC is one of the N-heterocyclic carbenes 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr), 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes), 3-methyl-1-phenacylimidazol-2-ylidene (MAI), and
3-methyl-1-picolylimidazol-2-ylidene (MPI), and diene is either NBD or COD. The complexes are
characterized by elemental analysis, 1H NMR and IR spectroscopies, mass spectrometry, and, in the case
of RhCl(NBD)(IMes) and RhCl(COD)(MAI), X-ray crystallography. The new Ag(I) carbene complexes
[Ag(IPr)2]PF6 and [Ag(IMes)2]PF6 are also reported.
创建时间：
2016-05-05
