Activation of Hydrogen and Hydrogenation Catalysis by a Borenium Cation
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https://figshare.com/articles/dataset/Activation_of_Hydrogen_and_Hydrogenation_Catalysis_by_a_Borenium_Cation/2483455
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The readily prepared borenium salt [(IiPr2)(BC8H14)][B(C6F5)4] (2) [IiPr2 = C3H2(NiPr)2] is shown to activate H2 heterolytically in the presence of tBu3P. Compound 2 also acts as a catalyst for the metal-free hydrogenation of imines and enamines at room temperature.
创建时间：
2016-02-20
