Efficient Synthesis of Imino-methano Tröger Bases by Nitrene Insertions into C–N Bonds
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https://figshare.com/articles/dataset/Efficient_Synthesis_of_Imino_methano_Tro_ger_Bases_by_Nitrene_Insertions_into_C_N_Bonds/2391637
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A direct nitrene insertion into C–N bonds is observed upon treatment of methano-Tröger bases with arylsulfonyl iminophenyliodinanes under copper and dirhodium catalysis. Novel cyclic imino-methano Tröger bases are obtained (55–88%). Enantiopure products (ee ≥ 99%) can be obtained with tailored substrates.
创建时间：
2016-02-19
