Organolutetium-Mediated Dearomatization and Functionalization of Pyrimidine Rings
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Organolutetium_Mediated_Dearomatization_and_Functionalization_of_Pyrimidine_Rings/2388730
下载链接
链接失效反馈官方服务：
资源简介：
The
synthesis of a pentadentate NNNNN bis(phosphinimine)carbazole
pincer ligand bearing two pyrimidine N-aryl rings is reported. A dialkyl
lutetium complex of the ligand, prepared by alkane elimination with
Lu(CH2SiMe3)3(THF)2, was
found to undergo an unusual transformation involving a double alkyl
shift whereby the −CH2SiMe3 groups on
the metal migrated to both pyrimidine rings. This migration afforded
a final product that featured alkyl-functionalized, dearomatized ligand
pyrimidine rings.
创建时间：
2016-02-19
