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Direct Formation of Propargyltin Compounds via C−H Activation

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Direct_Formation_of_Propargyltin_Compounds_via_C_H_Activation/2928124
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资源简介:
The mixed reagent SnC(SiMe3)2CH2CH2C(SiMe3)2]/ArI reacts with alkynes to give primary and secondary propargylic C−H activation. Alkynes tested include 1-phenylpropyne, 1-phenylbutyne, 1-trimethylsily1hexyne, and 2-hexyne. Aryl halides tested include iodobenzene and 2,4,6-triisopropyliodobenzene. An X-ray crystal structure is reported for the product of the secondary propargylic activation of 2-hexyne.
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2016-02-27
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