Expedient Two-Step Synthesis of Phenolic Cyclitols from Benzene
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https://figshare.com/articles/dataset/Expedient_Two_Step_Synthesis_of_Phenolic_Cyclitols_from_Benzene/3076588
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资源简介：
The benzeneselenol-catalyzed, tributyltin hydride-mediated addition of phenolic iodides to benzene gives
the 3-(hydroxyaryl)-1,4-cyclohexadienes, predominantly. Under conditions of controlled osmoylation,
these are converted to the racemic 1,2-syn-2,3-anti-3-(hydroxyaryl)-4-cyclohexene-1,2-diols, whereas
exhaustive osmoylation gives the 3-(hydroxyaryl)-3,5-dideoxymucoinositols, whose stereochemistry is
established by X-ray crystallography.
创建时间：
2016-03-01
