Ca3Na4LiBe4B10O24F: A New Beryllium Borate with a Unique Beryl Borate ∞2[Be8B16O40F2] Layer Intrabridged by [B12O24] Groups
收藏Figshare2016-02-22 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Ca_sub_3_sub_Na_sub_4_sub_LiBe_sub_4_sub_B_sub_10_sub_O_sub_24_sub_F_A_New_Beryllium_Borate_with_a_Unique_Beryl_Borate_sub_sub_sup_2_sup_Be_sub_8_sub_B_sub_16_sub_O_sub_40_sub_F_sub_2_sub_Layer_Intrabridged_by_B_sub_12_sub_O_sub_24_sub_Groups/2561095
下载链接
链接失效反馈官方服务：
资源简介：
A novel beryllium borate, Ca3Na4LiBe4B10O24F, has been discovered. It possesses a unique ∞2[Be8B16O40F2] layer composed of two opposite parallel [Be4B4O12F]∞ layers bridged with [B12O24] polyborates. The linkage of [B12O24] to other structural units is first found in anhydrous borates. In the ∞2[Be8B16O40F2] layer, multiple tunnels are arranged along different directions resided by the alkali and alkaline-earth cations. The compound remains stable in an ambient atmosphere from room temperature to the melting point at 830 °C and melts incongruently.
创建时间：
2016-02-22
