Bimetallic Organometallic Compounds of σ-gem-Diethynylethene (gem-DEE) Ligands: trans-Ru2(DMBA)4(gem-DEE)2
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https://figshare.com/articles/dataset/Bimetallic_Organometallic_Compounds_of_i_gem_i_Diethynylethene_i_gem_i_DEE_Ligands_i_trans_i_Ru_sub_2_sub_DMBA_sub_4_sub_i_gem_i_DEE_sub_2_sub_/2660320
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Reported herein are the preparation and characterization of trans-Ru2(DMBA)4(gem-DEE)2 compounds 1a/1b (gem-DEE = σ-geminal-diethynylethene), the first examples of redox active metal complexes containing gem-DEE ligands. DFT calculations revealed a significant mixing between the π(DEE) and π*/π(Ru2) orbitals in both the HOMO and HOMO-1 of the model compound 1′.
创建时间：
2016-02-23
