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Synthesis, Structure, and Methyl Methacrylate Polymerization Activity of a Mixed π-Ferrocene π-Toluene Complex of Potassium Tris(hexamethyldisilazide)magnesiate

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https://figshare.com/articles/dataset/Synthesis_Structure_and_Methyl_Methacrylate_Polymerization_Activity_of_a_Mixed_Ferrocene_Toluene_Complex_of_Potassium_Tris_hexamethyldisilazide_magnesiate/3346744
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资源简介:
Treating a toluene solution of mixed potassium−magnesium tris(hexamethyldisilazide) with ferrocene yields a surprising complex exhibiting simultaneous arene and metallocene π-coordination of K+, which when prepared in situ initiates the polymerization of MMA to give syndio-rich PMMA.
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2004-03-15
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