[Rh{NC5H3-2,6-(CH2PtBu2)2}(PCy3)][BArF4]: A Latent Low-Coordinate Rhodium(I) PNP Pincer Compound
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/_Rh_NC_sub_5_sub_H_sub_3_sub_2_6_CH_sub_2_sub_P_sup_t_sup_Bu_sub_2_sub_sub_2_sub_PCy_sub_3_sub_BAr_sup_F_sup_sub_4_sub_A_Latent_Low_Coordinate_Rhodium_I_PNP_Pincer_Compound/2621790
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资源简介：
An expedient new route to the cationic [(PNPtBu)Rh(L)]+ metal fragments (PNPtBu = κ3-NC5H3-2,6-(CH2P tBu2)2; L = CO, acetone, ethene, MeCN, N2) by the synthesis of, then substitution of PCy3 in, [(PNPtBu)Rh(PCy3)][BArF4] is reported. This synthetic route also allows for the synthesis of the new dihydrogen complex [(PNPtBu)Rh(H2)][BArF4]. [(PNPR)Rh(PCy3)][BArF4] (R= Ph, Cy, Mes) are also reported, in which the PCy3 ligand is more tightly bound to the metal center.
创建时间：
2016-02-23
