Asymmetric Induction in Hydroacylation by Cooperative Iminium Ion–Transition-Metal Catalysis
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https://figshare.com/articles/dataset/Asymmetric_Induction_in_Hydroacylation_by_Cooperative_Iminium_Ion_Transition-Metal_Catalysis/4047585
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资源简介:
A new
strategy for the rhodium-catalyzed enantioselective hydroacylation
is described. This has been achieved through the merger of iminium
ion catalysis and transition-metal catalysis such that asymmetric
induction derives from a readily accessible, inexpensive chiral nonracemic
secondary amine catalyst rather than a chiral nonracemic phosphine
as is typical of conventional asymmetric hydroacylation methods.
创建时间:
2016-10-31



