Highly Efficient, Regioselective, and Stereospecific Oxidation of Aliphatic C–H Groups with H<sub>2</sub>O<sub>2</sub>, Catalyzed by Aminopyridine Manganese Complexes
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Aminopyridine manganese complexes [LMnII(OTf)2] having a similar coordination topology catalyze the oxidation of unactivated aliphatic C–H groups with H2O2, demonstrating excellent efficiency (up to TON = 970), site selectivity, and stereospecificity (up to >99%).
创建时间:
2012-09-07



