Effects of condensation and dynamic exchange of phosphate diesters and hydroxyl groups

The datasets include all unprocessed files of all tested resins and dynamic materials used in the associated publication entitled Fundamental Insights into the Covalent Adaptable Networks of Phosphate Esters: Effects of Condensation and Dynamic Exchange of Phosphate Diesters with Hydroxyl Groups (Sustain. Mater. Technol. 2025 https://doi.org/10.1016/j.susmat.2025.e01270). The data sets consist of DMA storage modulus, loss modulus, tangent δ, stress-strain and stress relaxation (both tensile and flexural) of all relevant materials. All FT-IR spectra of comonomer blends, copolymers and homopolymers are included. Multiple DSC scans of polymer samples and DSC kinetic data on preheated samples are included in the appropriate folders (DSC General and DSC Kinetics). Thermogravimetric raw data are included in the TGA folder. P-NMR spectra are included for the four main copolymers tested before and after thermal processing.本数据集包含关联学术论文《磷酸酯基共价自适应网络的基础研究：磷酸二酯与羟基的缩合及动态交换效应》（发表于*Sustain. Mater. Technol. 2025*，DOI: 10.1016/j.susmat.2025.e01270）中所用全部待测树脂与动态材料的未处理原始文件。数据集涵盖所有相关材料的动态力学分析（Dynamic Mechanical Analysis, DMA）储能模量、损耗模量、损耗因子（tangent δ）、应力-应变曲线，以及拉伸与弯曲模式下的应力松弛数据。本数据集还收录所有共聚单体混合物、共聚物及均聚物的傅里叶变换红外光谱（Fourier Transform Infrared Spectroscopy, FT-IR）数据。聚合物样品的多次差示扫描量热法（Differential Scanning Calorimetry, DSC）扫描数据，以及预热样品的DSC动力学数据，分别收纳于对应文件夹"DSC General"与"DSC Kinetics"中。热重分析（Thermogravimetric Analysis, TGA）原始数据存放于TGA文件夹内。针对本次测试的四种主要共聚物，还提供了热加工前后的核磁共振磷谱（Phosphorus Nuclear Magnetic Resonance, P-NMR）数据。