Emission Energy Correlates with Inverse of Gold−Gold Distance for Various [Au(SCN)<sub>2</sub>]<sup>-</sup> Salts
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A series of bis(thiocyanato)gold(I) complexes with Au−Au interactions show luminescence in the range from 500 to 670 nm. The series of salts correlates emission energy with the reciprocal of the Au−Au distance. As the Au−Au distance increases, the emission energy decreases. The ligand system provides no framework for the Au−Au interaction. The emission energy seems totally determined by the Au−Au distance.
创建时间:
2004-01-14



