Mono- and Dimetalation of a Tridentate Bisimidazole-Phosphine Ligand
收藏NIAID Data Ecosystem2026-03-08 收录
下载链接：
https://figshare.com/articles/dataset/Mono_and_Dimetalation_of_a_Tridentate_Bisimidazole_Phosphine_Ligand/2257039
下载链接
链接失效反馈官方服务：
资源简介：
A bisimidazole-phosphine ligand,
PhP[(CH2)2ImArMe2]2, has
been prepared and has been metalated
using [Cp*Ru(μ3-Cl)]4, generating a bis(N-heterocyclic
carbene)-phosphine Ru(II) species through ligand coordination followed
by tautomerization. This is the first example of an NHC–donor–NHC
complex with two unsubstituted N–H wingtips. Furthermore, a
second metal center was installed by deprotonation of both N–H
wingtips and subsequent salt metathesis to generate Ru(II)–Fe(II)
and Ru(II)–Co(II) bimetallic complexes.
创建时间：
2016-02-16
