Synthesis of a High-Valent, Four-Coordinate Manganese Cubane Cluster with a Pendant Mn Atom: Photosystem II-Inspired Manganese–Nitrogen Clusters
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https://figshare.com/articles/dataset/Synthesis_of_a_High_Valent_Four_Coordinate_Manganese_Cubane_Cluster_with_a_Pendant_Mn_Atom_Photosystem_II_Inspired_Manganese_Nitrogen_Clusters/2536081
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资源简介：
High-valent, four-coordinate manganese imido- and nitrido-bridged
heterodicubane clusters have been prepared and characterized by single-crystal
X-ray diffraction and spectroscopic techniques. The title compound,
a corner-nitride-fused dicubane with the chemical formula [Mn5Li3(μ6-N)(N)(μ3-NtBu)6(μ-NtBu)3(NtBu)]
(1), has been prepared as an adduct with a nearly isostructural
tetramanganese cluster with one Mn atom replaced by Li. An important
feature of the reported chemistry is the formation of nitride from tert-butylamide, indicative of N–C bond cleavage
facilitated by manganese.
创建时间：
2016-02-21
