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Enantioselective Halocyclization Using Reagents Tailored for Chiral Anion Phase-Transfer Catalysis

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https://figshare.com/articles/dataset/Enantioselective_Halocyclization_Using_Reagents_Tailored_for_Chiral_Anion_Phase_Transfer_Catalysis/2497975
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A chiral anion phase-transfer system for enantioselective halogenation is described. Highly insoluble, ionic reagents were developed as electrophilic bromine and iodine sources, and application of this system to o-anilidostyrenes afforded halogenated 4H-3,1-benzoxazines with excellent yield and enantioselectivity.
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2012-08-08
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