Catalytic Synthesis of Luminescent Pyrimidines via Acceptor-less Dehydrogenative Coupling
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https://figshare.com/articles/dataset/Catalytic_Synthesis_of_Luminescent_Pyrimidines_via_Acceptor-less_Dehydrogenative_Coupling/13135471
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资源简介：
A simple
catalytic synthesis of luminescent pyrimidines from benzamidines
and alcohols is reported. These one-pot, acceptor-less dehydrogenative
coupling reactions are catalyzed by a ruthenium hydrido chloride complex
(1), supported by a chelating P^N ligand
(L1) bearing a benzannulated phenanthridine donor arm.
The pyrimidines thus produced are emissive in solution, with photoluminescence
quantum yields reaching 72%. Details of the catalytic synthesis and
characterization of the pyrimidines in both solution and the solid
state are reported, along with computational modeling of the emissive
excited states of representative examples.
创建时间：
2020-10-23
