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Solvent-Controlled Switchable Domino Reactions of MBH Carbonate: Synthesis of Benzothiophene Fused α‑Pyran, 2,3-Dihydrooxepine, and Oxatricyclodecene Derivatives

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NIAID Data Ecosystem2026-03-10 收录
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https://figshare.com/articles/dataset/Solvent-Controlled_Switchable_Domino_Reactions_of_MBH_Carbonate_Synthesis_of_Benzothiophene_Fused_Pyran_2_3-Dihydrooxepine_and_Oxatricyclodecene_Derivatives/5566630
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资源简介:
Solvent-controlled switchable domino reactions between 2-alkylidenebenzothiophene-3­(2H)-ones and Morita–Baylis–Hillamn (MBH) carbonate were developed. All domino reactions exhibited excellent regioselectivity, producing a broad spectrum of benzothiophene-fused α-pyran, 2,3-dihydrooxepine, and oxatricyclodecene derivatives. Furthermore, [4 + 2], [4 + 3], and related domino reactions from identical substrates can be controlled.
创建时间:
2017-11-09
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