Asymmetric Chlorination/Ring Expansion for the Synthesis of α‑Quaternary Cycloalkanones
收藏NIAID Data Ecosystem2026-03-08 收录
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A highly enantioselective chlorination/ring expansion cascade for the construction of cycloalkanones with an all-carbon quaternary center was realized (up to 97% ee). Oxa-cyclobutanol substrates were employed for the first time in the ring expansion reactions, affording the functionalized dihydrofuranones in excellent enantioselectivity.
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2016-02-17
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