Tetrathiophenalenyl Radical and its Disulfide-Bridged Dimer
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https://figshare.com/articles/dataset/Tetrathiophenalenyl_Radical_and_its_Disulfide_Bridged_Dimer/2927335
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The presence of two disulfide groups in the tetrathiophenalenyl radical TTPLY leads to a highly delocalized spin distribution and the lowest cell potential ever observed for a monofunctional phenalenyl derivative. While the heteroatom substituents successfully block C−C bond formation, TTPLY nonetheless associates in the solid state to afford the hypervalent S−S-bonded dimer (TTPLY)2.
创建时间:
2008-07-17



