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Tetrathiophenalenyl Radical and its Disulfide-Bridged Dimer

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NIAID Data Ecosystem2026-03-06 收录
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The presence of two disulfide groups in the tetrathiophenalenyl radical TTPLY leads to a highly delocalized spin distribution and the lowest cell potential ever observed for a monofunctional phenalenyl derivative. While the heteroatom substituents successfully block C−C bond formation, TTPLY nonetheless associates in the solid state to afford the hypervalent S−S-bonded dimer (TTPLY)2.

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2008-07-17
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