Rhodium-Catalyzed Addition–Cyclization of Hydrazines with Alkynes: Pyrazole Synthesis via Unexpected C–N Bond Cleavage
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https://figshare.com/articles/dataset/Rhodium_Catalyzed_Addition_Cyclization_of_Hydrazines_with_Alkynes_Pyrazole_Synthesis_via_Unexpected_C_N_Bond_Cleavage/2277883
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资源简介:
Rhodium-catalyzed
addition–cyclization of hydrazines with
alkynes has been achieved to afford highly substituted pyrazoles under
mild conditions. The cascade reaction involves two transformations:
addition of the C–N bond of hydrazines to alkynes via unexpected
C–N bond cleavage and intramolecular dehydration cyclization.
创建时间:
2016-02-17



