sp3 C–H Bond Activation with Ruthenium(II) Catalysts and C(3)-Alkylation of Cyclic Amines
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/sp_sup_3_sup_C_H_Bond_Activation_with_Ruthenium_II_Catalysts_and_C_3_Alkylation_of_Cyclic_Amines/2631088
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A selective C(3)-alkylation via activation/functionalization of sp3 C–H bond of saturated cyclic amines was promoted by (arene)ruthenium(II) complexes featuring a bidentate phosphino-sulfonate ligand upon reaction with aldehydes. This highly regioselective sustainable transformation takes place via initial dehydrogenation of cyclic amines and hydrogen autotransfer processes.
创建时间:
2016-02-23



