XMCD Studies on an [NPCl] Radical Bound to Osmium
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https://doi.esrf.fr/10.15151/ESRF-ES-2227849138
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资源简介:
We propose to conduct XMCD studies (Os L2,3-edge, P and Cl K-edge) on an S = ½ radical, [LnOs=NPCl], to determine local magnetic moments and spin-delocalization across its atoms. Despite consisting of just three atoms, the [NPCl] motif is unprecedented in any inorganic compound. An exact physical quantification of where its unpaired electron density resides (not resorting to calculations) is essential to unravel its chemical reactivity.
提供机构:
Lund University, Department of Chemistry, Centre for Analysis and Synthesis Box 124, 221 00, Lund, SWEDEN; ESRF, 71 avenue des Martyrs, CS 40220, 38043 Grenoble Cedex 9, France; Technical University of Denmark, Chemistry, Kemitorvet 206, 2800 Kgs. Lyngby, Denmark
创建时间:
2028-01-01



