XMCD Studies on an [NPCl] Radical Bound to Osmium

Name: XMCD Studies on an [NPCl] Radical Bound to Osmium
Creator: Lund University, Department of Chemistry, Centre for Analysis and Synthesis Box 124, 221 00, Lund, SWEDEN; ESRF, 71 avenue des Martyrs, CS 40220, 38043 Grenoble Cedex 9, France; Technical University of Denmark, Chemistry, Kemitorvet 206, 2800 Kgs. Lyngby, Denmark
Published: 2028-01-01T00:00:00+08:00

ESRF Portal2028-01-01 更新2026-04-23 收录

分子磁学表征

配位化学

数据链接：

https://doi.esrf.fr/10.15151/ESRF-ES-2227849138 数据链接链接失效反馈

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资源简介：

We propose to conduct XMCD studies (Os L2,3-edge, P and Cl K-edge) on an S = ½ radical, [LnOs=NPCl], to determine local magnetic moments and spin-delocalization across its atoms. Despite consisting of just three atoms, the [NPCl] motif is unprecedented in any inorganic compound. An exact physical quantification of where its unpaired electron density resides (not resorting to calculations) is essential to unravel its chemical reactivity.

提供机构：

Lund University, Department of Chemistry, Centre for Analysis and Synthesis Box 124, 221 00, Lund, SWEDEN; ESRF, 71 avenue des Martyrs, CS 40220, 38043 Grenoble Cedex 9, France; Technical University of Denmark, Chemistry, Kemitorvet 206, 2800 Kgs. Lyngby, Denmark

创建时间：

2028-01-01