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Pd-Catalyzed Stereoselective Carboperfluoroalkylation of Alkynes

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https://figshare.com/articles/dataset/Pd_Catalyzed_Stereoselective_Carboperfluoroalkylation_of_Alkynes/2131363
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资源简介:
A Pd-catalyzed three component reaction involving terminal alkynes, boronic acids, and perfluoroalkyl iodides is presented here. Trisubstituted perfluoroalkenes can be obtained in a highly regio- and stereocontrolled manner by the simultaneous addition of both aryl and CnFm groups across the triple bond in a radical-mediated process. The reaction is operationally simple offering a broad scope and functional group tolerance.
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2016-02-13
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