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Palladium-Catalyzed Intramolecular Selenocarbamoylation of Alkynes with Carbamoselenoates: Formation of α-Alkylidene-β-lactam Framework

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https://figshare.com/articles/dataset/Palladium_Catalyzed_Intramolecular_Selenocarbamoylation_of_Alkynes_with_Carbamoselenoates_Formation_of_Alkylidene_lactam_Framework/3277606
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Pd-catalyzed intramolecular selenocarbamoylation of alkynes leading to α-alkylidene-β-lactams was developed. This reaction can be applied to thiocarbamoylation and to the synthesis of δ- and ε-lactams and a cyclobutanone.
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2016-05-05
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