Van't Hoff law for temperature dependent Langmuir constants in clathrate hydrate nanocavities.

This work gives a set of parameters of van't Hoff law expression for calculating Langmuir constants of different gas species to determine their occupancy in clathrate hydrates in a temperature range 50 – 300 K. The van't Hoff law's parameters are derived from potential energy calculations using a pairwise site-site interaction model.