Ionothermal Synthesis of Chiral Metal Phosphite Open Frameworks with In Situ Generated Organic Templates
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https://figshare.com/articles/dataset/Ionothermal_Synthesis_of_Chiral_Metal_Phosphite_Open_Frameworks_with_In_Situ_Generated_Organic_Templates/2413606
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资源简介：
Two novel three-dimensional chiral
metal phosphite open frameworks with 4-connected quartz topology,
[Me2-DABCO][M2(HPO3)3]
[M = Co (1), Zn (2); Me2-DABCO
= N,N′-dimethyl-1,4-diazabicyclo[2.2.2]octane],
have been ionothermally synthesized in deep eutectic solvents (choline
chloride/1,3-dimethylurea). It is interesting that the organic template,
Me2-DABCO, is in situ generated from the alkylation reaction
of 1,4-diazabicyclo[2.2.2]octane and dimethyl phosphites.
创建时间：
2016-02-19
