Accessing Axially Chiral Biaryls via Organocatalytic Enantioselective Dynamic-Kinetic Resolution-Semipinacol Rearrangement
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https://figshare.com/articles/dataset/Accessing_Axially_Chiral_Biaryls_via_Organocatalytic_Enantioselective_Dynamic-Kinetic_Resolution-Semipinacol_Rearrangement/5063014
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资源简介：
We
have developed a synthetic strategy to access axially chiral
biaryls through a dynamic-kinetic resolution-semipinacol rearrangement
process. The axial chirality together with a sp3 quaternary
carbon can be introduced in a single chemical operation. The products
can be further ring-expanded to yield biologically relevant seven-membered
dibenzolactams with inverted axial chirality.
创建时间：
2017-06-01
