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The Diastereoselective Alkylation of Arenesulfenate Anions Using Homochiral Electrophiles

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/The_Diastereoselective_Alkylation_of_Arenesulfenate_Anions_Using_Homochiral_Electrophiles/2622198
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A series of Boc-protected β-amino sulfoxides were prepared by the reaction of arenesulfenate anions with chiral Boc-protected β-amino iodides. The stereoselective substitution reaction is believed to arise through precoordination of the sulfenate counterion with the nitrogen lone pair of the electrophile.
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2011-08-19
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