Materials Data on Pu(SO6)2 by Materials Project

PuO4(SO4)2 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Fddd space group. The structure is zero-dimensional and consists of sixteen sulfuric acid molecules and eight PuO4 clusters. In each PuO4 cluster, Pu is bonded in a distorted rectangular see-saw-like geometry to four equivalent O atoms. All Pu–O bond lengths are 1.80 Å. O is bonded in a single-bond geometry to one Pu atom.

PuO₄(SO₄)₂ 为四氟化硅衍生化合物，其晶体结构属于正交晶系（orthorhombic）Fddd空间群。该结构为零维结构，由16个硫酸分子与8个PuO₄团簇构成。在每个PuO₄团簇中，钚（Pu）原子以畸变的矩形跷跷板状配位几何构型，与4个等价的氧（O）原子成键；所有Pu-O键长均为1.80 埃（Å）。氧原子以单键配位构型与1个钚原子结合。