Mercuric Triflate-Catalyzed Tandem Cyclization Leading to Polycarbocycles
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https://figshare.com/articles/dataset/Mercuric_Triflate_Catalyzed_Tandem_Cyclization_Leading_to_Polycarbocycles/3302425
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资源简介：
We developed Hg(OTf)2-catalyzed cyclization of (E)-1,3-dimethoxy-5-(4-methyl-3-nonen-7-ynyl)benzene leading to the formation of (4aS*,10aS*)-3,4,4a,9,10,10a-hexahydro-5,7-dimethoxy-1,4a-dimethylphenanthrene in 98% yield with up to 100 catalytic turnovers. This is the first mercuric
salt-catalyzed biomimetic tandem cyclization.
创建时间：
2016-05-06
